Bis(Hexamethylene Triamine Penta (Methylene Phosphonic Acid)
NANJING FINECHEM HOLDING CO., LTD
Specifications
Item Index
Appearance Dark amber liquid
Active content % 43.0-48.0
Chloride (Cl-)% 6.0 max
Fe, mg/L 35.0 max
Density(20℃)g/cm3 1.20 min
pH(1%water solution) 2.0 max
Packing & Storage
Packing 200L plastic drum, IBC(1000L),customers' requirement.
Storage 20℃, 2 years.
Shipping Room temperature in China; may vary elsewhere
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General Information
Chemical & Physical Properties
Safety Information
Synthetic Route
Common Names Bis(hexamethylenetriaminepenta(methylenephosphonic acid))|phosphonic acid,[1,6-hexanediylnitrilobis(methylene)]pentakis
Structure
CAS No. 34690-00-1 Boiling Point (℃) 1002.7ºC at 760 mmHg
Molecular Weight 685.411 Melting Point (℃) N/A
Appearance Dark amber liquid Vapor Specific Gravity N/A
HS Code 2931900090 Flash Point (℃) 560.2ºC
Solubility Soluble in water and forms a transparent solution Autoignition Temperature (℃) N/A
Safety Phrases 26-36/37/39-45
RIDADR UN 3265
WGK Germany N/A
Packaging Group N/A
Hazard Class N/A
SYMPTOMS PREVENTION FIRST AID
Inhalation Cough. Sore throat. Use local exhaust or breathing protection. Fresh air, rest.
Skin Redness. Burning sensation. Itching. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Wear safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion Abdominal pain. Nausea. Vomiting. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
First, phosphoryl chloride (PCl3) is reacted with hexamethylene tetraamine (HMTA) in tetrahydrofuran (THF) to produce N,N',N''-hexakis(hexamethylene)triamine (HMTA6):

PCl3 + 6 HMTA → HMTA6 + 3 PCl5

Next, HMTA6 is reacted with formaldehyde (HCHO) in acetic acid (HOAc) to generate N,N',N''-hexakis(hexamethylene)triamine penta(methylene phosphonic acid) (Bis(Hexamethylene Triamine Penta (Methylene Phosphonic Acid))).

Frequently Asked Questions
What is BHMTPMPA?
BHMTPMPA is an efficient chelating scale inhibitor, which has good scale inhibition effect on carbonate scale and sulfate scale.
BHMTPMPA has excellent water solubility and thermal stability in a wide pH range and a high temperature of 120 °C, and has a high tolerance to calcium ions.
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